期刊
ELECTROCHIMICA ACTA
卷 198, 期 -, 页码 22-31出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.03.076
关键词
Structural phase transition; Fe3O4/reduced graphene oxide; Anode
资金
- National Natural Science Foundation of China [21576030, 51574090, 51304077]
- Science and Technology Department of Science and Technology of Project in Jiangsu Province [BY2014037-31]
- Privileged Development Program of Jiangsu High Education on New energy material science and engineering
- Opening Project of State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources [LAPS15001]
- Changzhou City Science and Technology Plan Projects [CE20150042]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Qing Lan Project of Education Department of Jiangsu Province
The electrochemical performance of a material varies with its structural phase transition. It is found that the rhombohedral Fe2O3 can transform to the cubic Fe3O4 via a calcination treatment in a nitrogen atmosphere, and lithium-ion storage performances of Fe3O4 get an obvious improvement due to its structural advantages. On the basis of data calculated by X-ray diffraction, the larger unit cell volume as well as the higher void fraction of cubic Fe3O4 provides lithium-ions with more transport channels for Li ions diffusion and storage without serious volume change, and thus the cubic Fe3O4 delivers an excellent reversible capacity of 921.1 mAh g(-1) after 15 cycles at the current density of 50 mA g(-1), which is much higher than 328.3 mAh g(-1) for the rhombohedral Fe2O3. To further enhance the structural stability of electrodes, reduced graphene oxide is introduced. The Fe3O4/reduced graphene oxide show an excellent specific capacity of 825.3 mAh g(-1) after 40 cycles and impressive rate performance of 600 mAh g(-1) at the current density of 400 mA g(-1), which are much higher than that of Fe3O4 (417 and 300 mAh g(-1)), Fe2O3 (137.4 and 95 mAh g(-1)) and Fe2O3/reduced graphene oxide (390.1 and 480 mAh g(-1)). These results demonstrate that the structural phase transition and reduced graphene oxide of Fe3O4/reduced graphene oxide composites offer unique characteristics suitable for high-performance energy storage application. (C) 2016 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据