期刊
ENERGY STORAGE MATERIALS
卷 34, 期 -, 页码 45-52出版社
ELSEVIER
DOI: 10.1016/j.ensm.2020.08.021
关键词
2d materials; Sodium ions storage; Lock-link structure; Tunable interlayer spacing; Diamine molecules
资金
- National Natural Science Foundation of China [201403099]
- Natural Science Funds for Distinguished Young Scholars of Gansu Province [1606RJDA320]
- State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals [SKLAB02019008]
- Ministry of Science and Technology, Taiwan [1082218-E-007045-, 1072923-E-007002-MY3, 1072218-E-007055, 1072112-M-007-030-MY3, 1092634-F-007023, 1092221-E-007048-]
Graphite, traditionally used in lithium-ion batteries, faces limitations due to its small interlayer spacing for sodium-ion insertion/extraction. An emerging approach involving chain-like H2N(CH2)xNH(2) between graphene oxide layers expands the interlayer spacing, enhances structure stability, and achieves excellent sodium storage performance.
Graphite has been commercialized as a material of lithium ions batteries because of its abundant source, low cost and excellent conductivity while the small interlayer spacing of graphite limits its application for Na+ insertion/extraction. Herein, an emerging and effective approach-chain-like H2N(CH2)xNH(2) locked between graphene oxide (GO) sheets to expand the interlayer spacing of graphene with enhanced stability of layered structure was demonstrated by a dehydration condensation reaction. The as-obtained H2N(CH2)xNH(2), which can link GO (xDM-GO), exhibits a lock-link structure, resulting in expanded interlayer spacing, with which the excellent Na+ storage performance with a high specific discharge capacity of 158.1 mAh g(-1) at 0.1 A g(-1) and outstanding capacity retention of 82.2% at a current density of 1 A g(-1) can be achieved. The effects of interlayer spacing on Na+ diffusion coefficient and the rate capability were investigated, for which 0.95 nm is the most suitable interlayer spacing for the Na+ insertion/extraction. The novel strategy demonstrates an effective way to controllably tune the interlayer spacing with the improved structure stability of GO, resulting in the best Na+ insertion/extraction behavior with the excellent Na+ storage performance.
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