期刊
ENERGY STORAGE MATERIALS
卷 36, 期 -, 页码 459-465出版社
ELSEVIER
DOI: 10.1016/j.ensm.2021.01.022
关键词
carbon nanotube; lithium metal; iron carbides; cryogenic TEM; cavity
资金
- National Natural Science Foundation of China [51372268, 22005334]
- National Key Development Program of China [2015CB251100]
The study successfully stored lithium metal in the cavities of carbon nanotubes and identified key factors contributing to the formation of metallic lithium through experimental characterization and theoretical calculations. These findings will facilitate the development of new methods for storing metals in the micro/nano pores or cavities of various carbons and other materials, as well as inspire strategies for improving metal deposition in secondary metal batteries.
The controversies on the metallic lithium storage in the carbon nano-pores have never stopped for more than three decades since Sato speculated the formation of Li-2 molecules in the porous carbon to explain its high lithium storage capacity. Herein, we successfully realized lithium metal storage in the cavities of the carbon nanotubes (CNTs) and directly observed the metallic lithium by the cryogenic transmission electron microscopy (cryo-TEM). By way of experimental characterization and theoretical calculations, we recognized that the capability of lithium-ion intercalation into the graphitic structure and the affinity of the iron carbides in the CNT cavities to lithium are critical to the formation of the metallic lithium therein. These findings will open up a new gate for metal storage in the micro/nano pores or cavities of various carbons and other materials as well as inspire new strategies for improving the metal deposition in the secondary metal batteries.
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