期刊
ELECTROCHIMICA ACTA
卷 222, 期 -, 页码 990-998出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.11.067
关键词
ultrathin carbon gauze; Friedel-Crafts crosslinking; hierarchically porous structure; high-rate performance; supercapacitor
资金
- National Natural Science Foundation of China [51502042, U1401246]
- Postdoctoral Science Foundation of China [2015M572278, 2016T90770]
- Science and Technology Program of Guangdong Province of China [2014B010106005, 2015B010135011]
- Science and Technology Program of Guangzhou City of China [201508030018]
Further increasing the output power is important to develop next-generation supercapacitor. In recent years, many papers focus on the design of pore structure to improve high-rate performance of supercapacitor, but few reports devote attention to reducing the nanoscale size of carbon framework to reach an optimal ion transfer. In the present paper, a novel ultrathin carbon gauze was fabricated by a simple boiling-induced volume expansion method. This carbon gauze shows foam-like morphology that is composed of 7 nm-thick carbon sheets. In addition, owing to the loose stack of carbon sheets, lots of meso-/macropores are created. When used as electrode in supercapacitor, the ultrathin carbon sheets can effectively minimize the electrolyte transfer distance and meso-/macropores can accelerate ion transfer speed, and then carbon gauze exhibits an impressive high-rate supercapacitive performance. While the scan rate is raised from 0.02 to 0.5 V s (1), the capacitance only reduces from 190 to 173 F g (1), implying a retention of 91%, and even under an extremely high scan rate of 2.0 V s (1), the cyclic voltammogram of carbon gauze still presents a symmetrically rectangular shape, revealing a considerable capacitance of 142 F g (1) (75% of the capacitance at 0.02 V s (1)). (C) 2016 Elsevier Ltd. All rights reserved.
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