The effects of zinc substitution on the electrical properties of MgNb2O6 thin films

The effects of zinc substitution on the electrical properties of sol-gel derived MgNb2O6 (Mg1-xZnxNb2O6; MZ(x)NO) thin films were investigated. Accordingly, the experimental results revealed that the optimal optical and electrical properties of the devices can be obtained for specimen with x = 0.2. The dielectric constant, average transparency and optical band gap of the devices at 400 degrees C annealing are 21.2 (@1 MHz), similar to 80% and 4.86 eV, respectively. The results indicated that the electrical properties of the sol-gel derived MgNb2O6 thin films are tuneable based upon the variation of zinc content. More importantly, the fabrication temperature of the MZ(0.2)NO thin films is 100 degrees C lower than the bending point of the glass substrate making it suitable for practical applications. With the increase of the applied electric field, the leakage conduction mechanisms of the Al/MZ(x)NO/ITO devices are mainly controlled first by ohmic conduction at low electric field, changes to space-charge-limited conduction (SCLC) and then FN tunneling at high electric field. Moreover, the critical electric field strength of the conduction mechanisms is also a function of the zinc content.

Automated summary

The study investigated the effects of zinc substitution on the electrical properties of sol-gel derived MgNb2O6 thin films, revealing that optimal performance was achieved at x = 0.2 and the electrical properties were tunable based on zinc content. Zinc content also influenced the leakage conduction mechanisms and critical electric field strength of the devices.