期刊
ELECTROCHIMICA ACTA
卷 196, 期 -, 页码 661-669出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.03.025
关键词
Oxygen evolution reaction; α -MnO2; Carbon sphere; Palladium; Core-shell structure
资金
- Natural Science Foundation of Guangdong Province [2014A030313521]
- Scientific Research Foundation for Yangcheng Scholar [1201561607]
- Science and Technology Program of Guangzhou [201510010112]
- National Natural Science Foundations of China [21276054, U1401246, 21376056]
Carbon spheres (CSs) with an average diameter of around 500 similar to 700 nm are prepared by a extended Stober method. Urchin-like MnO2 nanorods were deposited on the carbon spheres by hydrothermal method and the thickness of alpha-MnO2 shell is about 700 similar to 800 nm. Pd particles with a diameter of around 8 similar to 15 nm are dispersed on the surface of vertically aligned alpha-MnO2 rods which have a diameter of 40 similar to 50 nm. Three-dimensional (3D) Pd-MnO2/CS shows better activity and stability than Pd/CS and MnO2/CS for anodic oxygen evolution reaction (OER) in water electrolysis, which shows that Pd-doped urchin-like CS-MnO2 core-shell structure material would be a superiority catalyst for the OER. The onset potential shifts negatively and current density improves on the Pd-MnO2/CS for the OER, showing a synergistic effect between Pd and MnO2. (C) 2016 Elsevier Ltd. All rights reserved.
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