4.7 Article

Birnessite-type manganese dioxide nanoparticles embedded with nitrogen-doped carbon for high-performance supercapacitor

期刊

JOURNAL OF ENERGY STORAGE
卷 32, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.est.2020.101952

关键词

MnO2; Carbon materials; Nanoparticles; Nanocomposite; Supercapacitor

资金

  1. Ministry of Education in Saudi Arabia [IFKSURG-1438-026]

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In this study, we have fabricated manganese oxide nanoparticles embedded with N-doped carbon (MnO2/NDC) using egg albumin via hydrothermal and post calcination treatment. It was noticed that the MnO2 nanoparticles were grown into the nitrogen doped carbon matrix. As-fabricated NDC and MnO2/NDC show excellent surface area about to 685 m(2)/g and 645 m(2)/g respectively. The SEM and TEM images results revealed that the fabricated birnessite-type MnO2 nanoparticles are uniformly embedded into N-doped graphitic carbon matrix. The asymmetric super capacitor cell (ASC) was fabricated using the NDC and MnO2/NDC nanocomposites as a cathode and anode respectively and separated with whatman filter paper and 1.0 M Na2SO4 was used as electrolyte. The specific capacitance of the asymmetric supercapacitor is determine and found 895 F.g(-1) at 0.5A.g(-1) current density. The fabricated ASC show excellent charge and discharge properties and long term stability. The asymmetric NDC//MnO2/NDC cell supplies an excellent energy density about to 402.5 W h kg(-1) with power density about to 2250 W kg(-1). Therefore, these outcomes support that fabricated nanocomposite can be used as a potential electrode material for supercapacitor application.

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