期刊
PROCESSES
卷 9, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/pr9010175
关键词
magnetic copper ferrite nanospheres; extra-heavy crude oil; viscosity reduction; nanomaterial reuse
资金
- Spanish Project from ERDF/Ministry of Science, Innovation and Universities-State Research Agency [RTI2018-099, 224-B-I00]
- Junta de Andalucia, Spain [RNM-366]
This study focuses on the synthesis, use, and reuse of magnetic copper ferrite nanospheres (CFNS) to reduce the viscosity of extra-heavy oil. The CFNS were synthesized with a mean particle size of 150 nm and showed potential for repeated cycles of asphaltene adsorption and desorption. Rheology tests indicated that CFNS at a concentration of 500 mg/L achieved the highest viscosity reduction of 18%, with SiO2 nanoparticles showing similar results. The microstructure of extra-heavy oil changed significantly upon the addition of CFNS, as observed through a decrease in elastic and viscous moduli.
The main objective of this study is the synthesis, use, and reuse of magnetic copper ferrite nanospheres (CFNS) for extra-heavy oil viscosity reduction. The CFNS were synthesized using a solvothermal method resulting in mean particle size of 150 nm. Interactions of CFNS with the crude oil were evaluated through asphaltene adsorption isotherms, as well as static and dynamic rheology measurements for two cycles at 25 degrees C. Adsorption and desorption experiments corroborated that most of the asphaltenes adsorbed can be removed for nanoparticle reuse. During the rheology tests, nanoparticles were evaluated in the first cycle at different concentrations from 300 to 1500 mg/L, leading to the highest degree of viscosity reduction of 18% at 500 mg/L. SiO2 nanoparticles were evaluated for comparison issues, obtaining similar results regarding the viscosity reduction. After measurements, the CFNS were removed with a magnet, washed with toluene, and further dried for the second cycle of viscosity reduction. Rheology tests were performed for a second time at a fixed concentration of 500 mg/L, and slight differences were observed regarding the first cycle. Finally, changes in the extra-heavy oil microstructure upon CFNS addition were observed according to the significant decrease in elastic and viscous moduli.
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