期刊
CHEMISTRYSELECT
卷 5, 期 45, 页码 14438-14446出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202004115
关键词
photo-oxidation; alcohols; catalyst; covalent triazine frameworks; thiophene
资金
- China Scholarship Council
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy within the Exzellenzcluster 2186 The Fuel Science Center [390919832]
- RWTH Aachen University
- Projekt DEAL
Photocatalytic selective oxidation of aromatic alcohols by covalent organic frameworks (COFs) is a sustainable strategy to replace present metal-based heterogeneous catalytic oxidation systems. Covalent triazine-based frameworks (CTFs), a subgroup of COFs, possess promising properties as efficient catalysts for photocatalytic oxidation. Sulfur-containing metal-free CTFs exhibit a good performance in photocatalysis due to their narrowed band gap, and the fast generated photoelectrons/holes separation and transfer. Here, we report the synthesis of thiophene-based CTFs under mild conditions for photocatalytic oxidation of aromatic alcohols to the corresponding benzaldehydes using pure oxygen as the oxidant. Full conversion and a selectivity as high as 90 % to benzaldehyde were obtained paving the way for a potential application of these metal-free photocatalysts in fine chemicals synthesis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据