期刊
COATINGS
卷 10, 期 12, 页码 -出版社
MDPI
DOI: 10.3390/coatings10121154
关键词
tin; electrodeposition; cyclic voltammetry; deep eutectic solvent; nucleation
资金
- National Natural Science Foundation of China [5120403, 51804070]
The electrochemical behavior and electrodeposition of Sn were investigated in choline chloride (ChCl)-urea deep eutectic solvents (DESs) containing SnCl2 by cyclic voltammetry (CV) and chronoamperometry techniques. The electrodeposition of Sn(II) was a quasi-reversible, single-step two-electron-transfer process. The average transfer coefficient and diffusion coefficient of 0.2 M Sn(II) in ChCl-urea at 323 K were 0.29 and 1.35 x 10(-9) cm(2)center dot s(-1). The nucleation overpotential decreased with the increase in temperature and SnCl2 concentration. The results of the chronoamperometry indicated that the Sn deposition on tungsten electrode occurred by three-dimensional instantaneous nucleation and diffusion controlled growth using the Scharifker-Hills model. Scanning electron microscopy (SEM) showed that the morphology of the deposits is uniform, as a dense and compact film prepared by potentiostatic electrolysis on Cu substrate. X-ray diffraction (XRD) analysis revealed that the deposits were pure metallic Sn.
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