期刊
NANOMATERIALS
卷 11, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/nano11010058
关键词
nitrated graphene oxide; nitrification process; properties analysis; synchronous simultaneous analysis; combustion performance
类别
资金
- General Armament Department [9140A05080415BQ01]
- National Natural Science Foundation of China [21975024]
- Beijing Institute of Technology [20160242032]
A novel two-dimensional energetic material, nitrated graphene oxide (NGO), was synthesized via nitrification of graphite oxide, showing higher stability and storage performance, which has potential applications in catalysts, electrode materials, and energetic devices.
In order to synthesize a novel two-dimensional energetic material, nitrated graphene oxide (NGO) was prepared by the nitrification of graphite oxide to make a functional modification. Based on the morphological characterization, the NGO has a greater degree of curl and more wrinkles on the surface. The structure characterization and density functional theory calculation prove that epoxy and hydroxyl groups on the edge of graphite oxide have reacted with nitronium cation (NO2+) to produce nitro and nitrate groups. Hydrophobicity of NGO implied higher stability in storage than graphene oxide. Synchronous simultaneous analysis was used to explore the decomposition mechanism of NGO preliminarily. The decomposition enthalpy of NGO is 662.0 J center dot g(-1) and the activation energy is 166.5 kJ center dot mol(-1). The thermal stability is similar to that of general nitrate energetic materials. The hygroscopicity, thermal stability and flammability of NGO prove that it is a novel two-dimensional material with potential applications as energetic additives in the catalyst, electrode materials and energetic devices.
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