期刊
CHEMELECTROCHEM
卷 8, 期 1, 页码 195-208出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.202001436
关键词
NiMo; hydrogen evolution reaction; mechanisms; pH-dependent kinetics; thickness-dependent kinetics
Nickel-molybdenum alloys show superior hydrogen evolution reaction activity compared to nickel, and the HER process is controlled by the Heyrovsky step in acidic, near-neutral, and alkaline media. Increasing pH leads to higher hydrogen coverage, higher Tafel slope at low overpotentials, and ultimately only a single Tafel slope.
Nickel-molybdenum (NiMo) alloys can be a possible alternative to platinum as hydrogen evolution reaction (HER) catalysts because of the superior HER activity. However, the superior HER activity and the pH-dependent kinetics are not currently fully understood. Herein, we present a study of HER kinetics and mechanisms of NiMo in alkaline, near-neutral and acidic media by combining voltammetry measurements with electrochemical impedance spectroscopy and a microkinetic model. The results indicate that, compared to Ni, NiMo has significantly higher active surface area and intrinsic HER activity. In the subsequent measurements, we demonstrated that different from the existing explanations to the HER mechanisms for NiMo, the HER process in acidic, near-neutral, and alkaline media is controlled by the Heyrovsky step. Our results show that increasing pH increases the hydrogen coverage, which increases the Tafel-slope at low overpotentials, eventually resulting in only a single Tafel slope, which would commonly be interpreted as a Volmer-limited reaction. Furthermore, the studies of thickness effect on HER kinetics show that the HER kinetics of NiMo are thickness-dependent. In phosphate buffer, the increase in thickness did not significantly increase the double-layer capacitance, but simulations with the microkinetic model indicate that the active surface area still increased similarly to other electrolytes, which is likely related to the type of electrolyte used.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据