期刊
MICROMACHINES
卷 11, 期 12, 页码 -出版社
MDPI
DOI: 10.3390/mi11121090
关键词
perovskite film; MAPbI(3) microstructure; additive modulation; photodetectors; high detectivity
类别
资金
- National Key R&D Program of China [2018YFB0407102]
- Foundation of National Natural Science Foundation of China (NSFC) [61421002, 61675041, 51703019]
- Sichuan Science and Technology Program [2019YFH0005, 2019YFG0121, 2019YJ0178, 2020YFH0181]
- City University of Hong Kong [9610423, 9667199]
Organic-inorganic hybrid perovskites have been widely used as light sensitive components for high-efficient photodetectors due to their superior optoelectronic properties. However, the unwanted crystallographic defects of perovskites typically result in high dark current, and thus limit the performance of the device. Herein, we introduce a simple route of microstructures control in MAPbI(3) perovskites that associates with introducing an additive of 3,3,4,4-benzophenonetetracarboxylic dianhydridean (BPTCD) for crystallization adjustment of the perovskite film. The BPTCD additive can facilitate the formation of high-quality perovskite film with a compact and nearly pinhole-free morphology. Through characterizing the molecular interactions, it was found that the carbonyl groups in BPTCD is the key reason that promoted the nucleation and crystallization of MAPbI(3). As a result, we obtained high-efficient and stable perovskite photodetectors with low dark current of 9.98 x 10(-8) A at -0.5 V, an on/off ratio value of 10(3), and a high detectivity exceeding 10(12) Jones over the visible region.
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