期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 3, 页码 453-463出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202000636
关键词
aryl diazonium salts; C-C/C-heteroatom bond formations; radicals; photoredox catalysis
资金
- Natural Science Foundation of Zhejiang Province [LQ18B020001, LY18E020004]
- Public Welfare Project of Lishui [2016GYX01]
- College students Science and Technology Innovation Activity Plan of Zhejiang Province [2017R431006]
This review discusses the advances of aryl diazonium salts in light-mediated reactions, categorizing them into five groups based on the types of bond formations. Various reactions such as radical addition, metal-catalyzed coupling, and C-H activation are discussed in this context.
Aryl diazonium salts are important molecules in organic chemistry. This review discusses advances of their application in light-mediated reactions summarized in five categories according to the bond formations: (1) C-C formation from alkenes, alkynes, arenes, isocyanide, CO, arylboronic acid, or Grignard reagent. (2-5) C-B, C-N, C-S, and C-P formations. Reactions such as radical addition, elimination, metal-catalyzed coupling, C-H activation, cyclizations, and rearrangements will be discussed herein.
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