期刊
CHEMPLUSCHEM
卷 86, 期 4, 页码 540-548出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.202000760
关键词
heterogeneous catalysis; hydrogenation; imines; montmorillonite clays; palladium nanoparticles
资金
- DBT-PAN IIT Centre for Bioenergy (BT/EB/PANIIT/2012)
A new type of Pd nanoparticle-intercalated montmorillonite clay catalyst has been reported for the hydrogenation of 3-diphenyl prop-2-en-1-imine. The catalyst showed significant catalytic activity and selectivity under 5 bar pressure and a shorter reaction time. This developed catalytic system exhibited excellent reusability over five cycles, paving the way for industrial applications.
A series of palladium nanoparticles (Pd NPs) intercalated montmorillonite clay catalysts is reported for hydrogenation of 3-diphenyl prop-2-en-1-imine under mild reaction conditions. Pd/clay catalyst was prepared by a simple wet-impregnation method, and the physicochemical properties were characterized extensively by various techniques including N-2 adsorption, XRD, TEM, XPS and TPR etc., which showed the intercalation of active Pd NPs between the clay layers. The effect of reaction conditions such as catalyst loading, reaction time, temperature and H-2 pressure is explored, and thereby a plausible mechanism is proposed. The optimum amount of 6 wt % Pd/clay catalyst showed significant catalytic activity to yield 3-phenyl propyl aniline with 100 % conversion and selectivity under 5 bar pressure and a shorter reaction period of 3.5 h at 100 degrees C. The developed catalytic system unveiled excellent reusability over five cycles and hence paved the way for industrial applications.
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