Functionalized multi-walled carbon nanotubes and hydroxyapatite nanorods reinforced with polypropylene for biomedical application

Modified multi-walled carbon nanotubes (f-MWCNTs) and hydroxyapatite nanorods (n-HA) were reinforced into polypropylene (PP) with the support of a melt compounding approach. Varying composition of f-MWCNTs (0.1-0.3 wt.%) and nHA (15-20 wt.%) were reinforced into PP, to obtain biocomposites of different compositions. The morphology, thermal and mechanical characteristics of PP/n-HA/f-MWCNTs were observed. Tensile studies reflected that the addition of f-MWCNTs is advantageous in improving the tensile strength of PP/n-HA nanocomposites but decreases its Young's modulus significantly. Based on the thermal study, the f-MWCNTs and n-HA were known to be adequate to enhance PP's thermal and dimensional stability. Furthermore, MTT studies proved that PP/n-HA/f-MWCNTs are biocompatible. Consequently, f-MWCNTs and n-HA reinforced into PP may be a promising nanocomposite in orthopedics industry applications such as the human subchondral bone i.e. patella and cartilage and fabricating certain light-loaded implants.

Automated summary

The study reinforced modified multi-walled carbon nanotubes and hydroxyapatite nanorods into polypropylene using a melt compounding approach to create biocomposites of varying compositions with improved mechanical, thermal, and biocompatibility properties. The addition of modified multi-walled carbon nanotubes was found to enhance tensile strength but decrease Young's modulus of the nanocomposites, while both fillers improved thermal and dimensional stability of polypropylene. These nanocomposites show promise for orthopedic applications, particularly in human subchondral bone and lightweight implant fabrication.