Controlling nanochannel orientation and dimensions in graphene-based nanofluidic membranes

There is great interest in exploiting van der Waals gaps in layered materials as nanofluidic channels. Graphene oxide (GO) nanosheets are known to spontaneously assemble into stacked planar membranes with transport properties that are highly selective to molecular structure. Use of conventional GO membranes in liquid-phase applications is often limited by low flux values, due to intersheet nanochannel alignment perpendicular to the desired Z-directional transport, which leads to circuitous fluid pathways that are orders of magnitude longer than the membrane thickness. Here we demonstrate an approach that uses compressive instability in Zr-doped GO thin films to create wrinkle patterns that rotate nanosheets to high angles. Capturing this structure in polymer matrices and thin sectioning produce fully dense membranes with arrays of near-vertically aligned nanochannels. These robust nanofluidic devices offer pronounced reduction in fluid path-length, while retaining the high selectivity for water over non-polar molecules characteristic of GO interlayer nanochannels. Vertically stacked graphene oxide sheets are promising structures for molecular sieving technologies. By folding large planar sheets in an accordion-like manner, Liu et al. fabricate a thin robust filter with near-vertically aligned nanochannels geared towards commercial separation membranes.

Automated summary

The utilization of van der Waals gaps in layered materials as nanofluidic channels has sparked great interest. An approach using compressive instability in Zr-doped GO thin films is demonstrated to rotate nanosheets to high angles, creating wrinkle patterns that result in near-vertically aligned nanochannels. These robust nanofluidic devices significantly reduce fluid path-length while maintaining high selectivity for water over non-polar molecules characteristic of GO interlayer nanochannels.