期刊
TETRAHEDRON
卷 80, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2020.131867
关键词
Borylation; C-C bond Cleavage; Photocatalysis; Hemiacetal
资金
- Natural Science Foundation of China [21772003, 21933001, 22071004]
- China Postdoctoral Science Foundation [2020TQ0003]
- Boya Fellowship of Peking University
In this study, a photo-induced radical borylation of hemiacetal derivatives via C-C bond cleavage was reported. The transformation can be achieved under mild conditions with simple reaction settings and irradiation of visible light. Detailed mechanism studies through DFT calculations provided insights into the radical borylation process.
In this study, we reported a photo-induced radical borylation of hemiacetal derivatives via C-C bond cleavage. This transformation can be realized under mild conditions with simple reaction settings and irradiation of visible light. A series of substrates, including both cyclic and linear hemiacetal derivatives, were effectively transformed to the borylation product in moderate to good yields. Finally, the mechanism was studied in detail by DFT calculations, suggesting insight of the radical borylation process. (C) 2020 Elsevier Ltd. All rights reserved.
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