Synthesis and degradation behaviour of Zn-modified coating on Mg alloy

This study aimed to control the degradation of Mg-Zn-Ca alloy and improve its biocompatibility using a biodegradable Zn-modified calcium phosphate coating via dual-pulse electrodeposition. The formation mode and process of the coating were studied herein. Scanning electron microscopy revealed that the coating particles were compactly and neatly packed, and X-ray diffraction analysis, transmission electron microscopy, Fourier transform infrared spectrophotometer and X-ray photoelectron spectroscopy revealed that the coating comprises CaZn2(PO4)(2)center dot 2H(2)O. The introduction of Zn changes the formation mechanism of coating. The degradation behaviour of the coated Mg alloy was investigated via immersion test and electrochemical test in simulated body fluid. The results show that this non-stoichiometric Zn-modified calcium phosphate coating is biodegradable and has a better protective effect. In addition, the Zn-containing coating has hydrophilic property which is beneficial to enhance the cellular response to the implant's surface and increase apatite formation rate.

Automated summary

This study investigated the use of a biodegradable Zn-modified calcium phosphate coating to improve the biocompatibility of Mg-Zn-Ca alloy via dual-pulse electrodeposition. The results showed that the non-stoichiometric Zn-modified coating is biodegradable, has a protective effect, and enhances cellular response to the implant's surface. Additionally, the introduction of Zn changes the formation mechanism of the coating and increases the apatite formation rate.