Macromolecular Design of Lithium Conductive Polymer as Electrolyte for Solid-State Lithium Batteries

In the development of solid-state lithium batteries, solid polymer electrolyte (SPE) has drawn extensive concerns for its thermal and chemical stability, low density, and good processability. Especially SPE efficiently suppresses the formation of lithium dendrite and promotes battery safety. However, most of SPE is derived from the matrix with simple functional group, which suffers from low ionic conductivity, reduced mechanical properties after conductivity modification, bad electrochemical stability, and low lithium-ion transference number. Appling macromolecular design with multiple functional groups to polymer matrix is accepted as a strategy to solve the problems of SPE fundamentally. In this review, macromolecular design based on lithium conducting groups is summarized including copolymerization, network construction, and grafting. Meanwhile, the construction of single-ion conductor polymer is also focused herein. Moreover, synergistic effects between the designed matrix, lithium salt, and fillers are reviewed with the objective to further improve the performance of SPE. At last, future studies on macromolecular design are proposed in the development of SPE for solid-state batteries with high energy density and durability.

Automated summary

The development of solid-state lithium batteries has seen a growing interest in solid polymer electrolyte (SPE) due to its thermal and chemical stability, low density, and good processability. However, most SPE suffers from issues like low ionic conductivity and reduced mechanical properties, which can be addressed through macromolecular design with multiple functional groups. Future research should focus on the synergistic effects between the designed matrix, lithium salt, and fillers to improve the performance of SPE for batteries with high energy density and durability.