期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 253, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.seppur.2020.117528
关键词
Potassium; Aluminum; Leaching kinetics; Phosphorus-potassium associated ore; Hydrochloric acid
资金
- Local Science and Technology Development Project Guiding by China [2019ZYYD056]
- Special Technology Innovation Project of Hubei Province of China [2018ACA156]
- Open Project of State Key Laboratory of Efficient Utilization for Low Grade Phosphate Rock and Its Associated Resources [WFKF2019-05]
The leaching behaviours of potassium and aluminum from phosphorus-potassium associated ore in HCl-CaF2 media were investigated at temperature from 60 to 90 degrees C. The higher dissolved fraction of potassium compared with aluminum was found in this study though they were mainly incorporated into the same mineralogical phase of potash feldspar in the ore. Moreover, the dissolved fraction of potassium was always higher than aluminum in all the investigated conditions due to the existence of secondary precipitation phase such as amorphous aluminosilicate or the formation of insoluble AlF complex in the leaching process. In addtion, the leaching kinetic data were successfully examined by a semiempirical kinetic model based on the classical shrinking core model. It was found that there are two distinct stages in the leaching process and the kinetics of both stages follows the semiempirical kinetic model with chemical reaction being the rate-controlling step. The activation energies for potassium and aluminum from the ore were 39.031 and 44.260 kJ.mol(-1) at first leaching stage, and 59.274 and 62.944 kJ.mol(-1) at second leaching stage, respectively.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据