期刊
DYES AND PIGMENTS
卷 126, 期 -, 页码 194-201出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2015.12.002
关键词
Twisted intramolecular charge transfer (TICT); Aggregation induced emission (AIE); Thermochromism; Multi-colour emissions; Solvatochromism; Optical waveguides
Five cyano-functionalized 1,4-bis((E)-2-(1H-indol-3-yl)vinyl)benzene derivatives with a donor-acceptor acceptor-donor structure have been designed and synthesized. All the luminophores exhibit both twisted intramolecular charge transfer and aggregation induced emission characteristics. Meanwhile, significant fluorescence changes (up to 74-77 nm) were observed during their tandem photoluminescence experiments in cyclohexane/THF and THF/water systems. Most importantly, the constructed dyes present chain length-dependent thermochromic behaviour: (1) almost no thermochromism is observed for the three luminophores with relatively short alkyl chains; (2) as for the luminophore with N-tetradecyl groups, it initially exhibits greenish-yellow fluorescence which turns to orange upon heating and the orange emission is retained after cooling; (3) the luminophore with N-hexadecyl groups extraordinarily displays three-colour emissions including greenish-yellow, orange and salmon pink fluorescence in initial, heated and cooled states, respectively. Additionally, the three luminophores with poor thermochromic performance show optical waveguide properties, demonstrated by their fluorescence microscopy images. (C) 2015 Elsevier Ltd. All rights reserved.
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