期刊
RENEWABLE ENERGY
卷 161, 期 -, 页码 257-264出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.renene.2020.06.035
关键词
Potassium borohydride; Hydrogen evolution; Pd-complex; Catalyst; Hydrolysis
In this work, we aimed to present an efficient catalyst in potassium borohydride hydrolysis for hydrogen production. Therefore 5-Amino-2,4-dichlorophenol-3,5-ditertbutylsalisylaldimine-Pd complex was synthesized. FT-IR, SEM, TEM, BET, XRD, Elemental Analysis techniques was employed for characterization of Pd-complex catalyst. When the catalyst tested in KBH4 hydrolysis reaction, some affecting factors were studied such as temperatures (20 degrees C-50 degrees C), catalyst amounts (5-50 mg), KOH concentrations (0-10%) and KBH4 concentration (2-10%) The results displayed that the synthesized Palladium Schiff Base complex catalyst facilitates potassium borohydride hydrolysis with 25.194 kj/mol activation energy (Ea). Additionally, Pd Schiff Base complex demonstrated remarkable reusability performance and conserved 95% of its inherent catalytic activity even at sixth recycle. (C) 2020 Elsevier Ltd. All rights reserved.
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