期刊
REACTION KINETICS MECHANISMS AND CATALYSIS
卷 132, 期 1, 页码 1-35出版社
SPRINGER
DOI: 10.1007/s11144-021-01934-9
关键词
Silver molybdate; Visible light photocatalysis; Heterogeneous Fenton-like processes; Ag-based catalysts; Water; wastewater treatment
资金
- Brazilian Council for Scientific and Technological Development (CNPq-Brazil) [405892/2018 6, 301479/2018-6, 405223/2018-8]
This paper introduces the potential of silver molybdate (Ag2MoO4) as a catalyst in water/wastewater treatment, emphasizing its intriguing electronic properties and diverse morphologies, while also mentioning the current challenges in synthesis, properties, and characterization.
Advanced oxidation processes can achieve high degradation levels for various recalcitrant contaminants but the cost of their use in water/wastewater treatment is high. In recent years, more effective catalysts have been developed (such as silver molybdate) to minimize this and other drawbacks, offering a lower band gap and larger operational pH range. Silver molybdate (Ag2MoO4) has attracted attention due to its intriguing electronic properties, diversity of morphologies, and physico-chemical characteristics. Even more recently, catalytic activity in photocatalysis, Fenton-like processes, electrocatalysis and disinfection has been reported, highlighting the potential for its use in a broad range of important fields of application, including water and wastewater treatment. This paper provides a brief history of this semiconductor, mainly focusing on the current state of knowledge and the remaining challenges in terms of its synthesis (particularly obtaining the metastable tetragonal alpha-phase), properties and characterization. The application of Ag2MoO4 as a catalyst for application in advanced oxidation processes is also addressed.
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