Oceanic crust and mantle evidence for the evolution of Tonian-Cryogenian ophiolites, southern Brasiliano Orogen

Unravelling the complexity of tonian-cryogenian (950-680 Ma) evolution of ophiolites requires the search for rare mineral systems and their quantification with varied techniques. Ophiolites in the Brasiliano Orogen are widely distributed over 2,000 km along the eastern half of South America. We selected two ophiolites from different geotectonic settings of the Sul-Riograndense Shield, southern Brasiliano Orogen, to delimit the evolution of the oceanic phase of the orogen. The southern portion of the Bossoroca ophiolite is inserted in the Sao Gabriel juvenile terrane and contains rare metasomatic tourmaline in chloritite close to serpentinite and metamorphosed Cr-spinel. The southern Bossoroca ophiolite was intruded by Cerro da Cria and Ramada Granites and the U-Pb-Hf isotopic study of zircon from these rocks constrains the crustal evolution of the Sao Gabriel juvenile terrane. Capane ophiolite has similar age (793-715 Ma) as the Bossomca ophiolite and was inserted in the Porongos fold-thrust belt with preserved Cr-spinel of mantellic composition. Integrated use of Cr-spinel mineral chemistry, B isotopes in tourmaline in the Bossomca ophiolite and zircon U-Pb-Hf isotopes of granites associated with the southern Bossomca ophiolite revealed several steps in the evolution of the ophiolites in the Dom Feliciano Belt. Capane Cr-spinel cores have mantle-derived compositions (Mg# 0.66 - 0.69; Cr# 0.51 - 0.53), tourmaline from the Bossoroca ophiolite is dravite and has delta B-11 = 0 to + 3, and granites crystallization ages are 578 +/- 3.2 and 612 +/- 12 Ma (epsilon Hf-zrn = -10 to -25). Zircon from other dravite occurrences of the Bossoroca ophiolite were previously dated at 920 Ma. We unraveled the main steps in the evolution of ophiolites from the southern Brasiliano Orogen, with emphasis on the Bossomca and Capane ophiolites, during their trajectory from mid-ocean ridge (920 Ma), formation of dravite in oceanic crust, preservation of mantellic cores in Cr-spinel, and intrusion of craton-generated granites at 612-578 Ma.