期刊
POLYHEDRON
卷 194, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2020.114937
关键词
Silicon(IV) phthalocyanine; Fluorescence; Singlet oxygen; Photosensitizer; DNA/BSA binding
资金
- TUBITAK
A novel silicon(IV) phthalocyanine compound and its quaternized derivative were designed and synthesized, fully characterized, and their photophysical and photochemical properties were investigated. The addition of axial ligands showed an improvement in the properties of the compounds. Spectroscopic investigation of their binding behavior with BSA and DNA was also studied.
The novel axially bis[4-(4-pyridinyl)phenol] substituted silicon(IV) phthalocyanine (3) and its quaternized derivative (3Q) were designed and synthesized. These phthalocyanines were fully characterized by elemental analysis and different spectroscopic methods, such as FT-IR, UV-Vis, MALDI-TOF and 1H NMR. The photophysical and photochemical properties, such as electronic absorption, fluorescence emission, fluorescence lifetimes, singlet oxygen generation and photostability, of these phthalocyanines were investigated. These properties were examined in DMSO for the non-ionic phthalocyanine (3) and in both DMSO and aqueous solution for the ionic phthalocyanine (3Q). The addition of bis[4-(4-pyridinyl)phenol] groups as axial ligands showed an improvement of the photophysical and photochemical properties. In addition, a spectroscopic investigation of the binding behavior of the quaternized silicon(IV) phthalocyanine complex to bovine serum albumin (BSA) and DNA was also studied in this work. (C) 2020 Elsevier Ltd. All rights reserved.
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