期刊
POLYHEDRON
卷 193, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2020.114890
关键词
Ruthenium; Ruthenacycle; Carbamoyl; Hydrogenase mimics
资金
- Nanyang Technological University
- Ministry of Education [RG121/18]
The ruthenacyclic carbamoyl complexes with derivatized 4-position of the pyridinyl ring have been synthesized, serving as structural mimics of the metal cofactor of [Fe]-hydrogenase. The derivative with R = H reacts with phosphine to form a disubstituted product.
The ruthenacyclic carbamoyl complexes [RuBr(2-NHC(O)C5H3N-4-R)(CO)(2)(MeCN)] in which the 4-position of the pyridinyl ring is derivatized, have been synthesized. These are ruthenium-based structural mimics of the natural [Fe]-hydrogenase metal cofactor. The derivative with R = H reacts with phosphine to form a disubstituted product [RuBr(2-NHC(O)C5H4N)(CO)(PPh2SPh)(2)]. (C) 2020 Elsevier Ltd. All rights reserved.
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