期刊
ORGANOMETALLICS
卷 40, 期 3, 页码 306-309出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.0c00706
关键词
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资金
- National Natural Science Foundation of China [21672193]
- Ministry of Industry and Information Technology of the People's Republic of China [Z135060009002]
- 111 Project [D20003]
- Key Research Projects of Colleges and Universities in Henan Province [20A150040]
- Zhengzhou University of China [JC2020530190]
The report discusses the synthesis of a series of biphosphirane complexes from phosphiranide complexes, and the intramolecular dimerization of these complexes to yield 1,4-diphosphanorbornane derivatives catalyzed by binuclear Mn-2 (CO)(10). This work highlights the synthetic potential of transforming small phosphiranes to phospha-heterocycles through metal-catalyzed reactions.
In this report, a series of biphosphirane complexes 1 were synthesized from the phosphiranide complex. The binuclear Mn-2 (CO)(10)-catalyzed intramolecular dimerization of these biphosphirane complexes provided 1,4-diphosphanorbornane derivatives. This work demonstrates the synthetic possibility of transforming small phosphiranes to phospha-heterocycles by metal-catalyzed reactions.
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