期刊
ORGANIC LETTERS
卷 23, 期 1, 页码 160-165出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c03892
关键词
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资金
- National Natural Science Foundation of China [21971182, 21771131]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX20_2652]
A new efficient method has been developed for the photocatalytic P(O)-C(sp(2)) coupling of (hetero)aryl halides with H-phosphine oxides or H-phosphites under visible light or sunlight irradiation, yielding arylphosphine oxides and arylphosphonates. This method is widely tolerant to various functional groups and can proceed efficiently on a gram scale.
An efficient method has been developed for photocatalytic P(O)-C(sp(2)) coupling of (hetero)aryl halides with H-phosphine oxides or H-phosphites under the irradiation of visible light or sunlight. The thioxanthen-9-one/nickel dual catalysis mediates this phosphonylation to give arylphosphine oxides and arylphosphonates in moderate to excellent yields. This transformation is widely tolerant to a range of functional groups and proceeds efficiently on a gram scale.
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