期刊
ORGANIC LETTERS
卷 22, 期 24, 页码 9735-9739出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c03813
关键词
-
资金
- BRNS, India [37(2)/14/06/2017-BRNS]
- SERB, India [SR/S1/IC/56/2012, EMR/2017/003109]
- University Grants Commission, New Delhi (UPE program)
- University Grants Commission, New Delhi (CAS program)
- Department of Science and Technology, New Delhi (PURSE program)
- Department of Science and Technology, New Delhi (FIST program)
- SERBNPDF [PDF/2016/000685]
- UGC-DSKPDF [CH/1718/0252]
- DST-SERB-CORE [CRG/2019/005931]
- STARS [STARS/APR2019/CS/782/FS]
Meso-free B(III)subchlorin 1 has been realized exclusively for the first time from meso-ethoxycarbonyl-substituted tripyrrane along with the first subchlorin dimer 2 as its mu-oxo analogue via a facile one-pot approach. The subchlorin is highly stable toward oxidation; hence, it was not contaminated with the corresponding subporphyrin analogue 3. The subchlorin (56%) and its dimer (30%) exhibit singlet oxygen generation ability for the first time. The B-O-B dimer displays strong exciton coupling between the two macrocycles.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据