期刊
ORGANIC LETTERS
卷 23, 期 3, 页码 663-667出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c03721
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资金
- National Science Centre, Poland [UMO-2016/23/B/ST5/00177, POWR.03.02.00-00-I026/16]
- European Union through the European Social Fund under the Operational Program Knowledge Education Development
A bench-stable cobalt(II) complex, with a 3N-donor socket-type benzimidazole-imine-2H-imidazole ligand, is reported as an efficient precatalyst for regioselective hydrosilylation of terminal alkynes, providing high yields with excellent selectivity. This catalyst loading range of 0.5-0.05 mol % is among the most efficient reported for cobalt-catalyzed alkyne hydrosilylation in the literature.
A bench-stable cobalt(II) complex, with 3N-donor socket-type benzimidazole-imine-2H-imidazole ligand is reported as a precatalyst for regioselective hydrosilylation of terminal alkynes. Both aromatic and aliphatic alkynes could be effectively hydrosilylated with primary, secondary, and tertiary silane to give a-vinylsilanes in high yields with excellent Markovnikov selectivity and extensive functional-group tolerance. Catalyst loading varies within 0.5-0.05 mol %, which is one of the most efficient reported so far in the literature on cobalt-catalyzed alkyne hydrosilylation.
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