期刊
ORGANIC LETTERS
卷 23, 期 3, 页码 1060-1065出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c04257
关键词
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资金
- National Natural Science Foundation of China [21702108]
- Natural Science Foundation of Jiangsu Province, China [BK20160977]
- Six Talent Peaks Project in Jiangsu Province [YY-033]
- Tier 1 grant from the Ministry of Education of Singapore [M4012045.110 (RG12/18-S)]
- Distinguished University Professor grant, Nanyang Technological University, Singapore
A green method has been developed for the sulfination of allenic carbonyl compounds to access a wide variety of vinylic sulfones, which works in aqueous media under very mild conditions. The reaction is atom economic and can provide a moderate to excellent yield of diverse vinylic sulfones with wide functional group tolerance. The efficiency of this method has been demonstrated in reactions where the desired products can be isolated by filtration.
A green method for the sulfination of allenic carbonyl compounds to access a wide variety of vinylic sulfones is developed. This reaction works in aqueous media under very mild conditions. This reaction is atom economic. A wide variety of vinylic sulfones could be obtained in moderate to excellent yields with wide functional group tolerance. The efficiency of this method is demonstrated in some reactions where the desired products can be isolated by filtration.
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