期刊
OPTIK
卷 226, 期 -, 页码 -出版社
ELSEVIER GMBH
DOI: 10.1016/j.ijleo.2020.166028
关键词
Solution-processable; NBD-Cl; Charge transfer; Impedance spectroscopy; Cost-effective optoelectronics
类别
This study incorporated the small organic molecule NBD-Cl into the MEH-PPV polymer matrix, finding that a weight ratio of 1:0.5 achieved optimal charge transfer efficiency. Devices based on this composition showed improved current levels and reduced threshold voltage. Additionally, experimental impedance spectroscopy data revealed an effective charge mobility of 1.62 x 10(-3) cm(2) V(-1)s(-1).
The solution-processable small organic molecules have provoked the interest for their applications in cost-effective optoelectronic devices. This work presents the incorporation of the small organic molecules of 4-chloro-7-nitro-2,1,3-benzoxadiazole (NBD-Cl) into the MEH-PPV polymer matrix to enhance the performance of charge transport. The absorption and photoluminescence spectra were used to investigate the optical properties of the composite films. An optimal weight ratio of (1:0.5) of MEH-PPV:NBD-Cl is found to achieve the best efficiency of charge transfer. For the same composition, the device based on ITO/MEH-PPV:NBD-Cl/Al shows an improvement in current levels and reduction in threshold voltage. Additionally, by fitting the experimental impedance spectroscopy data, informations about the resistances and mobilities were extracted. The effective charge mobility are 1.62 x 10(-3) cm(2) V(-1)s(-1).
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