4.4 Article

Fragrance components of Gymnadenia conopsea and Gymnadenia odoratissima collected at several sites in Italy and Germany

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NATURAL PRODUCT RESEARCH
卷 36, 期 13, 页码 3435-3439

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TAYLOR & FRANCIS LTD
DOI: 10.1080/14786419.2020.1851227

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Gymnademia; scent; volatile organic compounds; solid phase microextraction; gas-chromatography; mass spectrometry

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The SPME-GC-MS analysis of Gymnadenia conopsea and Gymnadenia odoratissima varieties revealed differences in aroma components, which may play a role in pollinator attraction.
The SPME-GC-MS analysis of the aroma components of Gymnadenia conopsea subsp. conopsea, subsp. densiflora, var. alpina and Gymnadenia odoratissima var. odoratissima, var. idae were reported. The main components of in total 78 found in G. conopsea subsp. conopsea were elemicin, cis-9-hexadecenal, hexadecanal, isoelemicin and (Z)-11-hexadecen-1-ol acetate; in subsp. densiflora benzyl benzoate, eugenol and trans-isoeugenol; in var. alpina benzyl benzoate, methyleugenol and elemicin. In the scent of G. odoratissima var. odoratissima were found 2-phenylethyl acetate, eugenol and pentadecane, in var. idae mainly C15-C21 alkanes and C16, C18 carbonic acids and some isoprenoid-derivatives. As all tested Gymnadenia-taxa are allogamous, the differences in scent composition may play a role in pollinator attraction.

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