Fabrication and Characterization of Lignin/Dendrimer Electrospun Blended Fiber Mats

Blending lignin as the second most abundant polymer in Nature with nanostructured compounds such as dendritic polymers can not only add value to lignin, but also increase its application in various fields. In this study, softwood Kraft lignin/polyamidoamine dendritic polymer (PAMAM) blends were fabricated by the solution electrospinning to produce bead-free nanofiber mats for the first time. The mats were characterized through scanning electron microscopy, Fourier transform infrared (FTIR) spectroscopy, zeta potential, and thermogravimetry analyses. The chemical intermolecular interactions between the lignin functional groups and abundant amino groups in the PAMAM were verified by FTIR and viscosity measurements. These interactions proved to enhance the mechanical and thermal characteristics of the lignin/PAMAM mats, suggesting their potential applications e.g. in membranes, filtration, controlled release drug delivery, among others.

Automated summary

By blending softwood Kraft lignin with polyamidoamine dendritic polymer, bead-free nanofiber mats were successfully produced for the first time, showing enhanced mechanical and thermal characteristics. The chemical interactions between lignin functional groups and amino groups in PAMAM were verified, suggesting potential applications in membranes, filtration, and controlled release drug delivery.