期刊
MOLECULES
卷 26, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/molecules26010027
关键词
soluble alkylated flavins; bio-inspired materials; organic electronics; side-chain engineering; fused-ring systems; riboflavin; materials Science; general
资金
- Ministry of Industry and Trade TRIO [FV20022]
- Czech Science Foundation [17-24707S]
- Austrian Agency for International Cooperation in Education and Research (OEAD-GmbH, WTZ) [CZ01/2020, 8J20AT025]
- European Regional Development Fund (EFRE) within the project ENZYMBIOKAT [GZ2018-98279-2]
- Austrian Science Foundation (FWF) within the Wittgenstein Prize [Z222-N19]
A series of novel soluble nature-inspired flavin derivatives were synthesized and characterized, demonstrating their potential for delicate tuning of optical properties and thermal stability. Thin films prepared thereof exhibit high stability with smooth and homogeneous morphology.
A series of novel soluble nature-inspired flavin derivatives substituted with short butyl and bulky ethyl-adamantyl alkyl groups was prepared via simple and straightforward synthetic approach with moderate to good yields. The comprehensive characterization of the materials, to assess their application potential, has demonstrated that the modification of the conjugated flavin core enables delicate tuning of the absorption and emission properties, optical bandgap, frontier molecular orbital energies, melting points, and thermal stability. Moreover, the thin films prepared thereof exhibit smooth and homogeneous morphology with generally high stability over time.
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