期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 42, 期 3, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202000535
关键词
organocatalytic polymerization; polyesters; ring‐ opening polymerization; sustainable polymers
资金
- National Natural Science Foundation of China [51873211, 91856113]
- Jilin Science and Technology Bureau [20200301023RQ]
- Opening Foundations of Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, Jiangnan University [YJ 2020-01]
- State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University [KF2011]
The review highlights the use of various catalysts, especially metal-based catalysts, for controlled ROP of OCAs. It also summarizes recent progress on the organocatalytic ROP of OCAs and discusses the future development of this method for sustainable polyester synthesis.
Sustainable polyesters can be furnished via ring-opening polymerization (ROP) of O-carboxyanhydrides (OCAs). Various catalysts, especially metal-based catalysts, are devised to achieve controlled ROP of OCAs. In the following mini review, the recent progress on the organocatalytic ROP of OCAs, including the usage of thiourea-based bifunctional single-molecule organocatalysts for eliminating epimerization in OCAs polymerization is summarized. Moreover, the future development of the organocatalytic ROP of OCAs for the synthesis of sustainable polyesters will be discussed.
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