期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 42, 期 4, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202000617
关键词
anti-counterfeiting materials; Cu-coordination bonds; high-performance epoxy resins; toughening
资金
- National Natural Science Foundation of China [21973076, 21504073, 21202134, 11447215]
- Scientific Research Fund of Science and Technology on Plasma Physics Laboratory [6142A04180411]
- Sichuan Youth Science and Technology Foundation [2016JQ0055]
- Scientific Research Fund of Sichuan Provincial Education Department [18ZA0495, 16ZA0136]
By incorporating dynamic Cu-benzotriazole cross-links into high performance epoxy networks, this study successfully circumvents the inherent trade-off between strength and extensibility for epoxy resins, resulting in outstanding thermal stability and mechanical properties of the epoxy resins, while also imparting anti-counterfeiting function through local manipulation of coordination crosslinking.
It is of great significance to circumvent the inherent trade-off between strength and extensibility for epoxy resins. Herein dynamic Cu-benzotriazole cross-links are incorporated, as the appropriate intermolecular coordination interaction, into high performance epoxy networks, and the resulting epoxy resins exhibits outstanding thermal stability and mechanical properties, their strength and extensibility are simultaneously improved. Additionally, local manipulation of coordination crosslinking confers the film with anti-counterfeiting function.
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