l-Cysteine modified silver nanoparticles-based colorimetric sensing for the sensitive determination of Hg2+ in aqueous solutions

A simple and sensitive colorimetric sensing method was constructed for detection of Hg2+ in aqueous solutions and based on silver nanoparticles functionalized with l-cysteine (l-Cys-Ag NPs). In this method, adenosine triphosphate (ATP) induced aggregation of l-Cys-Ag NPs. Simultaneously, the solution colour changed from bright yellow to brown. In the presence of Hg2+, Hg2+ chelated ATP to form a complex and reduce the degree of aggregation of l-Cys-Ag NPs and was accompanied by a colour change from brown to bright yellow. The changing values of absorbance at 390 nm were linearly correlated with concentration of Hg2+ over the 4.00 x 10(-8) to 1.04 x 10(-6) mol center dot L-1 range, with a detection limit of 8 nM. This method was used successfully for detection of Hg2+ in real water samples and performed good selectivity and sensitivity. The recovery range was 91.5-109.1%, indicating that the method has vast application potential for determination of Hg2+ in the environment.

Automated summary

A colorimetric sensing method based on l-Cys-Ag NPs was developed for detecting Hg2+ in aqueous solutions. The method showed good selectivity and sensitivity, with a detection limit of 8 nM, and has vast application potential for determination of Hg2+ in the environment.