期刊
JOURNAL OF POROUS MATERIALS
卷 28, 期 3, 页码 651-659出版社
SPRINGER
DOI: 10.1007/s10934-020-00990-1
关键词
Sol-gel; Two-step surface modification; Compressive strength; MTMS; TMCS
资金
- National Natural Science Foundation of China [51972222, 51202157]
- Tianjin Research Program of Application Foundation and Advanced Technology [14JCQNJC02800]
- Independent Innovation Foundation of Tianjin University
High-strength silica aerogels were successfully prepared using a new two-step surface modification method, maintaining low density, high hydrophobicity, and significant compressive strength. This opens up the possibility of producing high-strength aerogel blocks through ambient pressure drying. The study also discusses the potential mechanism behind the improved mechanical properties achieved by the surface modification technique.
High-strength silica aerogels were prepared successfully by a new two-step surface modification (TSSM) method via ambient pressure drying (APD). Methyltrimethoxysilane (MTMS) and Trimethylchlorosilane (TMCS) were used as silylating agents in TSSM. First, MTMS is used to consume the residual pore water in the gel, and bridge the links between the secondary particles, further improving the structure of the Si-O-Si network. And then, TMCS is used in the second surface modification due to its smaller steric hindrance, higher reactivity, and more -CH3 groups, so that the -OH in the gel can be completely replaced by -CH3, thereby reducing the shrinkage and improving the hydrophobicity of aerogels during APD. On the basis of keeping the low density (0.1616 g/cm(3)), low thermal conductivity (0.0226 W m(-1) K-1)) and high hydrophobicity, the prepared samples also have high compressive strength (similar to 0.6 MPa) which is far greater than other silica aerogels at present, making it possible to prepare high-strength aerogel blocks via APD. Possible mechanism of the improvement of mechanical properties by TSSM is discussed.
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