期刊
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
卷 195, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.petrol.2020.107885
关键词
Emulsification; Micro-tomography; Surfactant; Phase behavior; Enhanced oil recovery
资金
- Saudi Aramco
Molecular-level forces experienced by a surfactant during emulsification can have a significant impact on emulsion structure and effective properties. Understanding the interplay of molecular-level forces and effective phase properties during in situ emulsification is a fundamental question relevant to various subsurface engineering applications. Herein, we use dynamic synchrotron-based X-ray microtomography to capture flow dynamics during an oil emulsification process, whereby brine salinity influences the predominate molecular-level forces. We measure oil recovery, phase viscosities, phase morphologies, contact angles and water relative permeability to elucidate the underlying oil recovery mechanisms. Optimum salinity formed a stable emulsion phase with ultra-low interfacial tension, viscosity high enough to reduce the mobility of the injected solution and a reduced adhesive force that resulted in less contact between oil and solid grains. These mechanisms are attributed to favorable flow dynamics that lead to improved oil recovery that can be tuned by brine salinity.
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