期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 931, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2020.121628
关键词
Luminescent iridium complexes; Mechanochromic luminescence; Near-infrared emission; Dinuclear iridium complex; Schiff base
资金
- China Postdoctoral Science Foundation [2019M651184]
- Fundamental Research Funds for the Central Universities [2412019QD007]
- Science and Technology Project of Jilin Provincial Education Department [JJKH20201167KJ]
- Key Scientific and Technological Project of Jilin province [20190701010GH]
- Development and Reform Commission of Jilin province [2020C035-5]
- National Natural Science Foundation of China [51902124, BSKJ201832]
Two new near-infrared emissive iridium complexes were designed and synthesized in this study, both showing mechanochromic luminescent behavior attributed to physical phase transformations from amorphization to crystallization.
Iridium(III) complexes with near-infrared (NIR) emission are still less well developed. In this work, two new NIR emissive monoand dinuclear iridium complexes were designed and synthesized via introducing the tetraphenlyethene Schiff base ligands. Interestingly, both complexes display mechanochromic luminescent (MCL) behavior, and the MCL mechanism can be attributed to the atypical physical phase transformations from amorphization to crystallization. (C) 2020 Published by Elsevier B.V.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
