期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 2, 页码 1448-1455出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c02155
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资金
- Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang [2019R01005]
The paper discusses a novel one-pot cascade reaction catalyzed/oxidized by the [Pd]/[Ag] system, involving two C-N bond and one C-C bond formations during the double annulation process to yield the desired products. The method is applicable to a wide range of readily available substrates and provides high yields.
A novel procedure for a one-pot cascade reaction of o-aminoacetophenones and aryl/aliphatic isocyanates catalyzed/oxidized by the [Pd]/[Ag] system was developed. The reaction involves two C-N bond and one C-C bond formations during the double annulation process and the desired indoloquinazolinones and derivatives were afforded up to 81% yields from readily available substrates with a tolerance of a broad variety.
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