A Bottleable Imidazole-Based Radical as a Single Electron Transfer Reagent

Reduction of 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenyl-1H-imidazol-3-ium chloride (1) resulted in the formation of the first structurally characterized imidazole-based radical 2. 2 was established as a single electron transfer reagent by treating it with an acceptor molecule tetracyanoethylene. Moreover, radical 2 was utilized as an organic electron donor in a number of organic transformations such as in activation of an aryl-halide bond, alkene hydrosilylation, and in catalytic reduction of CO2 to methoxyborane, all under ambient temperature and pressure.

Automated summary

The study successfully synthesized and characterized an imidazole-based radical 2, which was proven to be a single electron transfer reagent and utilized as an organic electron donor in various organic transformations under ambient conditions.