4.6 Article

Controllable synthesis and luminescence properties of one-dimensional La2O3 and La2O3:Ln3+ (Ln = Er, Eu, Tb) nanorods with different aspect ratios

期刊

JOURNAL OF LUMINESCENCE
卷 229, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.jlumin.2020.117663

关键词

Lanthanum hydroxides; Lanthanum oxides; Hydrothermal synthesis; Nanostructures; Luminescence properties

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资金

  1. National Natural Science Foundations of China [21807023, 31971304]
  2. Basic Research Foundation of Education Ministry of Hebei Province [QN2018010]
  3. Natural Science Foundation of Hebei Province [B2019201449, H2019201466, E2020201033]
  4. Priority Strategy Project of Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of the Ministry of Education [ts2019005]
  5. Second Batch of Top Youth Talent Support Program of Hebei Province
  6. Hebei University [2015JQ04]

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La(OH)(3) nanorods with different aspect ratios were successfully synthesized using a simple hydrothermal method without surfactant, catalyst, or template. Controlling the alkali source amount and reaction time is crucial for morphology and size of the La(OH)(3) products. The La2O3 nanorods obtained from La(OH)(3) samples show characteristic emissions when doped with lanthanide ions, indicating potential applications in lighting, optical displays, and optoelectronic devices.
La(OH)(3) nanorods with different aspect ratios have been successfully synthesized by a simple hydrothermal method without using any surfactant, catalyst, or template. The amount of the alkali source in the initial solution and reaction time play a key role in controlling the morphology and particle size of the La(OH)(3) products. Subsequently, the as-obtained La(OH)(3) samples are used as precursor to fabricate the La2O3 nanorods after an annealing process. The lanthanide ions Ln(3+) (Ln = Er, Tb, Eu) doped La2O3 samples exhibit characteristic emissions corresponding to the electronic transitions of the Ln(3+) ions. Moreover, the morphologies and sizes of the luminescent materials have a great influence on their luminescence properties. Based on the unique luminescent properties and controllable morphology and size, these luminescent materials may find potential applications in fields such as lighting, optical displays, and optoelectronic devices.

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