High-efficiency core-shell magnetic heavy-metal absorbents derived from spent-LiFePO4 Battery

Search for simple and efficient recycling methods to utilize spent lithium-ion batteries is crucial for achieving sustainable resource development and reducing the hazardous materials released from the spent batteries. Herein, we have developed a new strategy to utilize the spent LiFePO4 batteries by utilizing the cathode plate as raw material to synthesize mesoporous core-shell adsorbent Mm@SiO2 (Mm denoted as the magnetic material) through a simple alkaline leaching process. The as-converted material exhibits excellent adsorption capacity when it has been used to remove heavy metal ions in heavy metal polluted water. The adsorption capacities for Cu2+, Cd2+, and Mn2+ have been achieved up to 71.23, 80.31 and 68.73 mg g(-1), respectively. The detailed adsorption mechanism has been elucidated with comprehensive characterization techniques, including TEM, XPS, NEXAS, and EXAFS, the edge shared [Cu2O8] bipyramids can be fit against the EXAFS data to represent the atomic-scale local structure after Mm@SiO2 adsorbs Cu2+. The present work demonstrates a novel routine to reutilize the spent lithium batteries, which is of great importance to achieve sustainable development based on the waste-to-treasure and waste-to-control-waste strategy for simultaneously reducing the hazardous release from industrial solid waste and heavy metal polluted water.

Automated summary

The study presents a new strategy to utilize spent LiFePO4 batteries by synthesizing mesoporous core-shell adsorbent from the cathode plate, achieving efficient adsorption of heavy metal ions in polluted water. The method shows high adsorption capacities for Cu2+, Cd2+, and Mn2+ ions and elucidates the detailed adsorption mechanism through comprehensive characterization techniques.