期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 851, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.156922
关键词
Glucose-derived carbon; Hierarchical porous structure; Dispersant; Chemical activation; Supercapacitive performance
资金
- National Natural Science Foundation of China (CN) [U1304203]
- 111 Project (CN) [B12015]
- Natural Science Foundation of Henan Province (CN) [162300410258]
- College Students Innovation and Entrepreneurship Training Program of ZZU (CN) [2020cxcy014]
Porous carbon materials were fabricated using a hydrothermal precarbonisation-calcination strategy with SDS as the dispersant and ZnCl2 as the activation agent, resulting in a hierarchical porous structure with a large specific surface area and total pore volume. The optimized sample, SAGC-1-4, showed enhanced supercapacitive performance with high specific capacitance and excellent rate performance in a symmetric supercapacitor configuration.
Compared with bulk materials, porous electrodes possess superior supercapacitive performance due to the effective enlarged specific surface areas, which have aroused tremendous attention in recent years. In this work, porous carbon materials derived from glucose were facilely fabricated via a hydrothermal precarbonisation-calcination strategy using sodium dodecyl sulfate (SDS) as the dispersant and ZnCl2 as the activation agent. Benefitting from the uniform dispersion of SDS and the activation effect of ZnCl2, the optimised sample, SAGC-1-4, possesses a hierarchical porous structure with large specific surface area (2360 m(2) g(-1)) and huge total pore volume (1.241 cm(3) g(-1)), leading to an enhanced supercapacitive performance. As a result, SAGC-1-4 presented a specific capacitance of 303.02 F g(-1) at 1.0 A g(-1) in the three-electrode configuration. Meanwhile, the SAGC-1-4-based symmetric supercapacitor displayed an excellent rate performance with a high energy density of 31.59 Wh kg(-1) at a power density of 400.00 W kg(-1) in comparison with many carbon materials previously reported. Thus, our work offers an effective strategy for the fabrication of porous carbon for high-performance energy conversion and storage devices. (C) 2020 Elsevier B.V. All rights reserved.
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