期刊
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
卷 27, 期 12, 页码 1695-1702出版社
SPRINGER
DOI: 10.1007/s12613-020-2169-y
关键词
molten carbonates; cyclic voltammetry; electro-reduction; inert anode; Invar36 alloy
The Fe-Ni36 alloy was prepared via the one-step electrolysis of a mixed oxides precursor in a molten Na2CO3-K2CO3 eutectic melt at 750 degrees C, where porous Fe2O3-NiO pellets served as the cathode and the Ni10Cu11Fe alloy was an inert anode. During the electrolysis, NiO was preferentially electro-reduced to Ni, then Fe2O3 was reduced and simultaneously alloyed with nickel to form the Fe-Ni36 alloy. Different cell voltages were applied to optimize the electrolytic conditions, and a relatively low energy consumption of 2.48 kWhkg(-1) for production of FeNi36 alloy was achieved under 1.9 V with a high current efficiency of 94.6%. The particle size of the alloy was found to be much smaller than that of the individual metal. This process provides a low-carbon technology for preparing the Fe-Ni36 alloy via molten carbonates electrolysis.
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