期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 46, 期 18, 页码 10801-10808出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.12.163
关键词
Amine boranes; Chemical hydrogen storage; Solubility; Enthalpy of solution; Entropy of solution
资金
- Robert Ramsay Chair Fund of The University of Alabama
Experimental determination of solubility and enthalpy of solution for various amine boranes in different solvents revealed differences in dissolution processes, with dimethyl sulfoxide solutions being the most exothermic. Increased methyl-substitution on the amine led to more endothermic processes. The study also validated the accuracy of density functional theory in predicting solubility of amine borane materials in polar solvents through comparison with experimental values.
Amine boranes are solid hydrogen storage materials and are difficult to transport within systems unless dissolved in solvents. The solubility and free energy of solution were experimentally determined for ammonia borane, methylamine borane, dimethylamine borane, trimethylamine borane, and tert-butylamine borane in methanol, ethanol, 1propanol, 2-propanol, acetonitrile, dimethyl sulfoxide, and tetrahydrofuran. The solubilities of ammonia borane/methylamine borane mixtures in methanol were also measured. The enthalpy of solution was experimentally determined for ammonia borane, methyl amine borane, dimethylamine borane, and 30/70 wt% ammonia borane/methylamine borane eutectic in four different solvents: methanol, ethanol, acetonitrile, and dimethyl sulfoxide. For all solutes, dimethyl sulfoxide solutions were the most exothermic or least endothermic. Increased methyl-substitution on the amine led to more endothermic processes. For methanol, ethanol, and acetonitrile, the entropy of solution increased as solubility increased. The entropy of solution for ammonia borane dissolving in dimethyl sulfoxide is negative. COSMO-RS solubility calculations using density functional theory optimized geometries agree relatively well with experimental values for amine borane materials dissolved in polar solvents. (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据