4.4 Article

Polymerizable Ionic Liquid-derived Non-precious Metal Catalyst Fe-N/C for Oxygen Reduction Reaction

出版社

ESG
DOI: 10.20964/2021.01.71

关键词

Polymerizable ionic liquid; Non-precious metal catalyst; Oxygen reduction reaction; Fuel cell

资金

  1. PAPD
  2. (Priority Academic Program Development of Jiangsu Higher Education Institutions)
  3. Natural Science Research Project of Jiangsu Higher Education Institutions [17KJB480005]
  4. National Natural Science Foundation of China [21776219]
  5. Postdoctoral Science Foundation of China [2018M631746]

向作者/读者索取更多资源

Polymerizable ionic liquid was used to prepare Fe-N/C non-precious metal catalyst for ORR, showing promising catalytic performance. The material has potential to be a precursor for ORR catalyst without noble metal.
Polymerizable ionic liquid (Pit) of hydrolyzed vinyl imidazolium nitrate ([HVim]NO3) was used to prepare the non-precious metal catalyst (NPMC) of Fe-N/C. The material was characterized for catalytic performance toward oxygen reduction reaction (ORR). The onset and half wave potential for ORR is 0.90 and 0.64 V-RHE, respectively. The electrochemical tests show that the Fe-N/C material is a potential NPMC for ORR. Therefore, the PIL is a promising precursor for ORR catalyst free of noble metal.

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